By K. Christmann (auth.), H.P. Bonzel (eds.)
Surface technology is known as a comparatively younger medical self-discipline, curious about the actual and chemical houses of phenomena on fresh and lined reliable surfaces, studied below a number of stipulations. The adsorption of atoms and molecules on sturdy surfaces is, for instance, the sort of , hooked up with roughly drastic alterations of all floor houses. An adsorption occasion is often saw in nature and located to be of technical value in lots of commercial procedures. therefore, floor technological know-how is interdisciplinary by means of its very nature, and as such a big middleman among basic and utilized research.
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Extra info for Adsorbed Layers on Surfaces. Part 5: Adsorption of molecules on metal, semiconductor and oxide surfaces
Performed at 130 K LEED 77Boz 85Mor1 82Imb; 92Nic 85Mor1 93Ham1 82Imb unknown metastable metastable metastable annealing reqd. T-dept. PT annealing reqd. T-dept. 0 74Chr 4-fold HREELS 78And2 4-fold HREELS 86Kar 79Chr1 expts. 0 Criti- Experical mental temp. method [K] He transmission ion channeling LEED Reference expts. 00 LEED metastable metastable metastable metastable metastable metastable 84Pen LEED pairing-row reconstr. 5 <175 <175 <220 >220 missing-row reconstr. expts. performed at 84Jon 150 K, missing-row reconstruction assumed expts.
1 Adsorbate properties of hydrogen on solid surfaces Criti- Experical mental temp. 58 Å Reference 96Mer local buckling reconstruction; expts. at 40 K 2-fold (short bridge) expts. performed at 130 K LEED 77Boz 85Mor1 82Imb; 92Nic 85Mor1 93Ham1 82Imb unknown metastable metastable metastable annealing reqd. T-dept. PT annealing reqd. T-dept. 0 74Chr 4-fold HREELS 78And2 4-fold HREELS 86Kar 79Chr1 expts. 0 Criti- Experical mental temp. method [K] He transmission ion channeling LEED Reference expts.
For more details and definitions, we refer to the chapters 1 and 2 of this Landolt-Börnstein subvolume III/42A (which you can find in parts 1 and 2, respectively) and to the specific literature [77Hie, 69Tra]. , [91Chr]). Since the exponential term of the PolanyiWigner equation (Eq. 6) contains the desorption energy, it is straightforward to deduce this quantity from an appropriate evaluation (Arrhenius plot) of a TD data set [75Bau1, 75Kin, 83Hab]. It is also possible to measure heats released by adsorption directly by calorimetry.